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描述有机化学反应机理
Book DescriptionIn revising this text for the second edition, a major goal was to make the book more user-friendly for both graduate and undergraduate students. Introductory material has been fleshed out. Headings have been added to make it easier to locate topics. The structures have been redrawn throughout, with added emphasis on the stereochemical aspects of reaction mechanisms. Coverage of some topics such as solvent effects and neighboring group effects has been expanded, and Chapter 6 has been completely reorganized and extensively rewritten.
基本介绍
- 书名：描述有机化学反应机理
- 出版社：世界图书出版公司
- 页数：471页
- ISBN：7506265958
- 作者：A.Miller 等
- 出版日期：2004年4月1日
- 开本：16开
- 品牌：世界图书出版公司北京公司
Preface to the Second Edition
Preface to First Edition
1 Introduction—Molecular Structure and Reactivity
1. How to Write Lewis Structures and Calculate Formal Charges
2. Representations of Organic Compounds
3. Geometry and Hybridization
4. Electronegativities and Dipoles
5. Resonance Structures
6. Aromaticity and Antiaromaticity
7. Tautomers and Equilibrium
8. Acidity and Basicity
9. Nucleophiles and Electrophiles
Preface to Second Edition
2 General Principles for Writing Reaction Mechanisms
1. Balancing Equations
2. Using Arrows to Show Moving Electrons
3. Mechanisms in Acidic and Basic Media
4. Electron-Rich Species: Bases or Nucleophiles?
5. Trimolecular Steps
6. Stability of Intermediates
7. Driving Forces for Reactions
8. Structural Relationships between Starting Materials and Products
9. Solvent Effects
10. A Last Word
1. Balancing Equations
2. Using Arrows to Show Moving Electrons
3. Mechanisms in Acidic and Basic Media
4. Electron-Rich Species: Bases or Nucleophiles?
5. Trimolecular Steps
6. Stability of Intermediates
7. Driving Forces for Reactions
8. Structural Relationships between Starting Materials and Products
9. Solvent Effects
10. A Last Word
Preface to Third Edition
3 Reactions of Nucleophiles and Bases
1. Nucleophilic Substitution
2. Eliminations at Saturated Carbon
……
4 Reactions Involving Acids and Other Electrophiles
5 Radicals and Radical Anions
6 Pericyclic Reactions
7 Additional Problems
Appendix A Lewis Structures of Common Functional Groups
Appendix B Symbols and Abbreviations Used in Chemical Notation
Appendix C Relative Acidities of Common Organic and Inorganic Substances
Index
1. Nucleophilic Substitution
2. Eliminations at Saturated Carbon
……
4 Reactions Involving Acids and Other Electrophiles
5 Radicals and Radical Anions
6 Pericyclic Reactions
7 Additional Problems
Appendix A Lewis Structures of Common Functional Groups
Appendix B Symbols and Abbreviations Used in Chemical Notation
Appendix C Relative Acidities of Common Organic and Inorganic Substances
Index
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